- PII
- S30345545S0044461825050046-1
- DOI
- 10.7868/S3034554525050046
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume 98 / Issue number 5
- Pages
- 322-332
- Abstract
- Исследована серия однокомпонентных катализаторов на основе комплексов палладия с фосфин-тиоэфирными лигандами в полимеризации этилена, а также сополимеризации этилена с норборненом. Установлено влияние условий реакции (природы растворителя, концентрации катализатора, температуры реакции) на характеристики продуктов (co-)полимеризации. Строение продуктов (co-)полимеризации этилена изучено с использованием H, C ЯМР-спектроскопии. Применение фосфин-тиоэфирных комплексов в качестве катализаторов полимеризации этилена приводит к образованию низкомолекулярных продуктов. Выбор типа катализатора существенно влияет на состав и микроструктуру продуктов сополимеризации этилена с норборненом.
- Keywords
- Date of publication
- 01.01.2026
- Year of publication
- 2026
- Number of purchasers
- 0
- Views
- 57
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