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RAS Chemistry & Material ScienceЖурнал прикладной химии Russian Journal of Applied Chemistry

  • ISSN (Print) 0044-4618
  • ISSN (Online) 3034-5545

GAS TRANSPORT PROPERTIES OF POLYNORBORNENES WITH Si—O—C FRAGMENTS IN SUBSTITUENTS (Review)

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PII
S30345545S0044461825070018-1
DOI
10.7868/S3034554525070018
Publication type
Article
Status
Published
Authors
F. A. Andreyanov
  • Occupation: Ph.D.
  • Affiliation: A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
M. V. Bermesev
  • Occupation: Dr. Sci., Associate Professor
  • Affiliation: A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
Volume/ Edition
Volume 98 / Issue number 7-8
Pages
412-424
Abstract
The review systematizes and analyzes the literature data on the effect of the structure of Si—O—C fragments in the side substituents of addition and metathesis polynorbornenes on their gas transport properties. The influence of the number and nature of alkoxysilyl groups, the length of alkyl and alkoxy fragments, the degree of branching of substituents, the presence of bridging and additional oxygen-containing or fluorine-containing groups is considered. It is shown that the variation of the structure of the organosilicon substituent makes it possible to purposefully change the gas permeability and selectivity of membranes, achieving an optimal combination of these parameters for the tasks of hydrocarbon separation and acid gas (CO, HS) recovery. Thus, the introduction of short alkoxy groups [tris(methoxy)silyl] leads to higher CO permeability and CO/N selectivity compared to polymers with longer substituents, and an increase in the number of oxygen-containing fragments in the substituents leads to an increase in selectivity due to a decrease in N permeability. The presence of fluorine-containing groups promotes an increase in CO solubility and, as a consequence, an increase in CO/CH selectivity. Special attention is paid to the identification of structure-property correlations and the definition of structures that provide high CO permeability while maintaining or increasing CO/N and CO/CH selectivity. The prospects for the use of such polymers for the creation of high-performance membranes and directions for further research are discussed.
Keywords
полинорборнены углекислый газ газоразделение мембраны газотранспортные свойства
Date of publication
01.01.2026
Year of publication
2026
Number of purchasers
0
Views
45

References

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