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RAS Chemistry & Material ScienceЖурнал прикладной химии Russian Journal of Applied Chemistry

  • ISSN (Print) 0044-4618
  • ISSN (Online) 3034-5545

SOLVOMETALLURGICAL PROCESSING OF FERRUGINOUS WASTE FROM CARBONYL NICKEL PRODUCTION

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PII
S30345545S0044461825070048-1
DOI
10.7868/S3034554525070048
Publication type
Article
Status
Published
Authors
A. Yu. Sokolov
  • Occupation: Ph.D.
  • Affiliation: I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials of the Kola Science Centre of the Russian Academy of Sciences (ICTREMS KSC RAS)
A. G. Kasikov
  • Occupation: Ph.D., Associate Professor
  • Affiliation: I.V. Tananaev Institute of Chemistry and Technology of Rare Elements and Mineral Raw Materials of the Kola Science Centre of the Russian Academy of Sciences (ICTREMS KSC RAS)
Volume/ Edition
Volume 98 / Issue number 7-8
Pages
441-448
Abstract
The work is devoted to the solvometallurgical processing of ferruginous waste from carbonyl nickel production of JSC «Kola MMC» — bottom residue afterburning, the main components of which are iron(III), nickel(II), chromium(III) and cobalt(II). It is shown that the use of solvometallurgical leaching of afterburning residues with octanol-1 saturated with hydrochloric acid makes it possible to combine the processes of leaching and selective extraction of iron(III) in one stage, resulting in the formation of two phases during leaching — an aqueous phase containing non-ferrous metals and an organic phase containing iron(III). It was established that under optimal process conditions — solid:liquid ratio = 1:25, T = 50°C, c(HCl) = 3.36 M — within 1 h, the total extraction of iron(III), nickel(II), cobalt(II) and chromium(III) is 93.2, 85.3, 70.5 and 80.8%, respectively, with 92% Fe(III), 1.2% Ni(II), 12.0% Co(II) and less than 0.1% Cr(III) passing into the extractant phase. The resulting de-ironed hydrochloric acid solution of non-ferrous metals can be sent for separation of non-ferrous metals, and the iron-containing extract after washing from non-ferrous metal impurities can be sent for re-extraction with subsequent production of iron(III) chloride solution and regeneration of the extractant.
Keywords
сольвометаллургия никелевые отходы железо(III) октанол-1 соляная кислота
Date of publication
01.01.2026
Year of publication
2026
Number of purchasers
0
Views
41

References

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